Recent Publications
2024
Ion-Selective Potentiometry with Plasma-Initiated Covalent Attachment of Sensing Membranes onto Inert Polymeric Substrates and Carbon Solid Contacts, Choi K.R.; Honig, ML.; Bühlmann, P. Analytical Chemistry 2024 [Full Text]
Non-covalent modification of graphene-based chemical sensors, Zhen, X.; Bühlmann, P.; Koester, S. J. US patent 11,923,419 B2, March 5, 2024
Hydrophilic Redox Buffers for Textile-Based Potentiometric Sensors, Herrero, E. J.; Goto, T.; Bühlmann, P. Sensors and Actuators B 2024 [Accepted]
Microporous Ag/AgCl on a Titanium Scaffold for Use in Capillary Reference Electrodes, Robinson, E.; Troudt, B.; Bühlmann, P. Analytical Chemistry 2024 [Accepted]
Chemical Sensors with Non-Covalent, Electrostatic Surface Modification of Graphene, Zhen, X.; Buhlmann, P.; Koester, S.; Nelson, J., US Patent 11,867,596 B2; patent issued Jan 9, 2024
2023
Effect of Ion Identity on Capacitance and Ion-to-Electron Transduction in Ion-Selective Electrodes with Nanographite and Carbon Nanotube Solid Contacts, Rousseau, C.; Chipangura, Y.; Stein, A.; Bühlmann, P. Langmuir, 2023, [Accepted]
Design Criteria for Nanostructured Carbon Materials as Solid Contacts for Ion-Selective Sensors, Chipangura, Y. E.; Spindler, B. D.; Bühlmann, P.; Stein, A. Adv mater, 2023, Full text
Covalently Attached Ionophores to Extend the Working Range of Potentiometric pH Sensors with Poly(decyl methacrylate) Sensing Membranes, Choi K.R.; Honig ML.; Bühlmann, P. Analyst 2023, [Accepted]
Determination of Forced Convection Effects on the Response of Membrane-Based Ion-Selective Electrodes via Numerical Solution to the Navier-Stokes-Nernst-Plank-Poisson Equations, Andrews, AJ.; Bühlmann, P.; Hogan, C J. Chem. Eng. Sci. 2023, Full text
Influence of the Composition of Plasticizer-free Silicone-based Ion-selective Membranes on Signal Stability in Aqueous and Blood Plasma Samples, Spindler, B.; Graf, K.; Dong, X.; Kim, M.; Chen, X.; Bühlmann, P.; Stein, A. Anal. Chem. 2023, [Accepted]
Ion-Selective Electrodes with Sensing Membranes Covalently Attached to Both the Inert Polymer Substrate and Conductive Carbon Contact, Choi, K. R.;Troudt, B. K., Bühlmann, P. Angewandte Chemie 2023, Full Text
Spontaneous Mesoporosity-Driven Sequestration of Ionic Liquids from Silicone-Based Reference Electrode Membranes, Dong, X.; Spindler, B.; Kim, M.; Stein, A.; Bühlmann, P. ACS Sensors 2023, 8, 4, 1774–1781 Full Text
Choi, K. R.; Lin, Y.; Mitzel, K.; McGuire, C.; Bühlmann, P. “Ion-selective Electrodes With Sensing Membranes Covalently Attached to Both an Inert Polymer Substrate and Conductive Carbon Contact” U.S. Provisional Patent Application 63/672,289; filed April 13, 2023.
Chen, X.; Stein, A.; Buhlmann, P.; “Reference Electrodes Including Silicone-Containing Polymer and Ionic Liquid”, U.S. 11,573,194 B2, patent issued February 7, 2023
Comparison of Copper(II) Oxide Nanostructures with Different Morphologies for Nonenzymatic Glucose Sensing, Fan, B.; Spindler, B. D.; Zhao, W.; Chan, H; Wang, Z.; Kim, M.; Chipangura, Y.; Bühlmann, P.; Stein, A. ACS Appl. Nano Mater. 2023, 6, 2, 1475–1486 Full Text
2022
Machine Learning-Based Rapid detection of Volatile Organic Compounds in a Graphene Electronic Nose, Capman, N. S. S.; Zhen, X. V.; Nelson, J. T.; Chaganti, V. R. S. K.; Finc, R. C.; Lyden, M. J.; Williams, T. L.; Freking, M.; Sherwood, G. J.; Bühlmann, P.; Hogan, C. J.; Koester, S. J. ACS Nano 2022 Full Text
The Effect of Paper on the Detection Limit of Paper-based Potentiometric Chloride Sensors, Herrero, E. J.; Troudt, B. K.; Bühlmann, P. Anal. Chem. 2022, 94, 43, 14898–14905. Full Text
Comparison of the Kinetics of Aldehyde Sensing by Covalent Bond Formation with Hydrazines and Hydroxylamines, Troudt, B. K.; Vue, J. W., Bühlmann, P. Tetrahedron 2022,119, 132852. Full text
Hu, J.; Buhlmann, P.; Stein, A.; Zhen, X. “Electrochemical Sensors with a Chemically Attached Molecular Redox Buffer”, US 11,307, 165 B2, patent issued April 19, 2022
Hydrogels Doped With Redox Buffers as Transducers for Ion-Selective Electrodes, Rousseau, C. R.; Honig, M. L.; Bühlmann, Anal. Chem. 2022, 94, 1143–50. Full text
Zhen, X.; Buhlmann, P.; Koester, S.; Nelson, J. “Chemical Sensors with Non-Covalent Electrostatic Surface Modification of Graphene”, US Patent 11,293,914 B2; patent issued April 5, 2022
Ion-Selective Potentiometric Sensors with Silicone Sensing Membranes: A Review, Chen, X. V.; Bühlmann, Current Opinion in Electrochemistry 2022, 32, 100896. Full text
Recent Progress in the Development of Improved Reference Electrodes for Electrochemistry, Troudt, B. K.; Rousseau, C. R.; Dong, X. I. N.; Anderson, E. L.; Bühlmann, P. Anal. Sci. 2022, 38, 71–83. Full text
2021
Solid-Contact pH Sensor with Covalent Attachment of Ionophore and Ionic Sites to a Poly(decyl methacrylate) Matrix, Choi, K.; Chen, X.; Buhlmann, P., Analytical Chemistry 2021, 93, 16899-16905. Full text
Zhen, X.; Buhlmann, P.; Koester, S.; Zhang, Y.; Nelson, J. “Chemical Sensors with Non-Covalent Surface Modification of Graphene”, US Patent 11,079,371 B2; patent issued August 3, 2021.
Potentiometric Sensors with Polymeric Sensing and Reference Membranes Fully Integrated into a Sample-Wicking Polyester Textile, Herrero, E.J., Bühlmann, P., Analysis and Sensing 2021, 1, 188–195. Full text.
Easy-to-Make Capillary-Based Reference Electrodes with Controlled, Pressure-Driven Electrolyte Flow, Anderson, E., Troudt, B., Bühlmann, P., ACS Sensors 2021, 6, 2211–2217. Full text.
Calibration-Free Potentiometric Sensing With Solid-Contact Ion-Selective Electrodes, Rousseau, C., Bühlmann, P., Trends in Anal. Chem. 2021, 140, 116277. Full text
2020
Rethinking Graduate Recruitment Weekends in the Digital Age, Gavin, J. T.; Nguyen, A. G.; Plasek, E. E.; Stathopoulos, S. M.; Bühlmann, P.; Tonks, I. A.; Roberts, C. C., J. Chem. Ed. 2020, 97, 2544–2555. Full text.
Ultra-Clean Graphene Transfer using a Sacrificial Fluoropolymer Layer and Self-Assembled Monolayers, Su, Q.; Zhen, X. V.; Nelson, J.; Bühlmann, P.; Sherwood, G.; Koester, S., ACS Appl. Mat. Interfac. 2020, 3, 11998–12007. Full text.
Fluorous-Phase Ion-Selective pH Electrodes: Electrode Body and Ionophore Optimization for Measurements in the Physiological pH Range, Chen, X.; Mousavi, M.; Bühlmann, P. ACS Omega 2020, 23(5), 13621–13629.
Fluorous-Phase Ion-Selective pH Electrodes: Electrode Body and Ionophore Optimization for Measurements in the Physiological pH Range, Chen, X.; Mousavi, M.; Bühlmann, P. ACS Omega, 2020, 5 (23) 13621-13629. full text.
Reference Electrodes Based on Ionic Liquid Doped Reference Membranes with Biocompatible Silicone Matrixes, Chen, X; Stein, A.; Bühlmann, P. ACS Sensors, 2020, 5(6),1717-1725. full-text
Solid-Contact Ion-Selective and Reference Electrodes Covalently Attached to Functionalized Poly(ethylene terephthalate), Anderson, E.; Chopade, S.; Spindler, B.; Stein, A.; Lodge, T.; Hillmyer, M.; Bühlmann, P. Anal. Chem, 2020, 92 (11) 7621–7629. full text
Critical Comparison of Reference Electrodes with Salt Bridges Contained in Nanoporous Glass with 5, 20, 50, and 100 nm Diameter Pores Anderson, E. L., Troudt, B., Bühlmann, P. Analytical Sciences, 2020, 36(2), 187. full text
2019
Ionic Liquid-based Reference Electrodes for Miniaturized Ion Sensors: What Can Go Wrong?, Mousavi, M. P. S.; Abd El-Rahman, M. K.; Tan, E. K.; Sigurslid, H. H.; Arkan, N.; Lane, J. S., Bühlmann, P., Whitesides, G. Sens. Actuators B, 2019, 301, 127112. full text
Indirect Potentiometric Determination of Polyquaternium Polymer Concentrations by Equilibrium Binding to 1-Dodecyl Sulfate, Anderson, E. L.; Samaniego, P. D.; Bühlmann, P. Anal. Sci. 2019, 35, 679–684. full text
More than a Liquid Junction: Effect of Stirring, Flow Rate, and Inward and Outward Electrolyte Diffusion on Reference Electrodes with Salt Bridges Contained in Nanoporous Glass. Anderson, E. L.; Lodge, T. P.; Gopinath, T.; Veglia, G.; Bühlmann, P. Anal. Chem. 2019, 91 (12), 7698−7704. full text
Potentiometric Selectivities of Ionophore-Doped Ion-Selective Membranes: Concurrent Presence of Primary Ion or Interfering Ion Complexes of Multiple Stoichiometries. Yilmaz, I.; Chen, L. D.; Chen, X. V.; Anderson, E. L.; da Costa, R. C.; Gladysz, J. A.; Bühlmann, P. Anal. Chem. 2019, 91(3), 2409-2417. full text
Remediation of Perfluorooctylsulfonate Contamination by in Situ Sequestration: Direct Monitoring of PFOS Binding to Polyquaternium Polymers, Anderson, E. L., Mousavi, M. P. S., Aly, Y. H., Chen, X. V., Simcik, M. F., Buhlmann, P. ACS Omega, 2019, 4 (1), 1068-1076. full text
2018
In-Situ Sensing of the Neurotransmitter Acetylcholine in a Dynamic Range of 1 nM to 1 mM, Abd El-Rahman, M.; Mousavi, M. S.; Mahmoud, A.; Abdelsalam, R.; Buhlmann, P. ACS Sens., 2018, 3(12), 2581-2589. full text
Stress and mental health in graduate school: How student empowerment creates lasting change, Mousavi, M. P. S.; Sohrabpour, Z.; Anderson, E. L.; Stemig-Vindedahl, A.; Golden, D.; Christenson, G.; Lust, K.; Bühlmann, P. J. Chem. Ed., 2018, 95(11), 1939-1946. full text
Redox Buffer Capacity of Ion-Selective Electrode Solid Contacts Doped with Organometallic Complexes, Zhen, X. V.; Rousseau, C. R.; Buhlmann, P. Anal. Chem., 2018, 90, 11000-11007 full text
Non-Covalent Surface Modification of Graphene Using Pyrene and Cyclodextrin Derivatives, Zhen, X. V.; Swanson, E.; Nelson, J.; Zhang, Y.; Su, Q.; Koester, S.; Buhlmann, P. ACS Appl. Mater. Interfac. 2018, 1, 2718-2726. full text
Cleaning of pH Selective Electrodes with Ionophore-Doped Fluorous Membranes in NaOH Solution at 90 ºC, Lugert-Thom, E. C.; Gladysz, J. A.; Rabai, J.; Bühlmann, P. Electroanalysis 2018, 30, 611-618. full text
Functionalized Mesoporous Polymers with Enhanced Performance as Reference Electrode Frits, Anderson, E. L.; Saba, S. A.; Loomis, D. J.; Buhlmann, P.; Hillmyer, M. A., ACS Appl. Nano Mat. 2018, 1, 139–144. full text
Paper-Based All-Solid-State Ion-Sensing Platform with a Solid Contact Comprising Colloid-Imprinted Mesoporous Carbon and a Redox Buffer, Hu, J.; Zhao, W.; Bühlmann, P.; Stein, A., ACS Appl. Nano Mat. 2018, 1, 293–301. full text
Elucidating the Role of AgCl in the Nucleation and Growth of Silver Nanoparticles in Ethylene Glycol, Chen, S.; Carey, J. L., III; Whitcomb, D. R.; Bühlmann, P.; Penn, R. L., Cryst. Growth Des., 2018, 18, 324–330. full text
2017
Capacitive Sensing of Glucose in Electrolytes Using Graphene Quantum Capacitance Varactors, Zhang, Y.; Ma, R.; Zhen, X.; Kudva, Y.; Buhlmann, P.; Koester, S., ACS Appl. Mater. Interfaces 2017, 9, 38863–38869. full text
Self-supporting, Hydrophobic, Ionic Liquid-Based Reference Electrodes Prepared by Polymerization-Induced Microphase Separation, Chopade, S. A.; Anderson E. L.; Schmidt, P. W.; Lodge, T. P.; Hillmyer M. A.; and Bühlmann P., ACS sensors 2017, 2, 1498–1504. full text (selected as an ACS Editors' Choice highlight)
Semifluorinated Polymers as Ion-Selective Electrode Membrane Matrix, Carey, J. L. III; Hirao, A.; Sugiyama, K.; Buhlmann, P., Electroanalysis 2017, 29, 739–747. full text
2016
Avoiding Errors in Electrochemical Measurements: Effect of Frit Material on the Performance of Reference Electrodes with Porous Frit Junctions, Mousavi, M. P. S.; Saba, S. A.; Anderson, E. L.; Hillmyer, M. A;. Buhlmann, P., Anal. Chem. 2016, 88, 8706–8713 full text
One-Dimensional Ionic Self-Assembly in a Fluorous Solution: The Structure of Tetra-n-butylammonium Tetrakis[3,5-bis(perfluorohexyl)phenyl]borate in Perfluoromethylcyclohexane by Small-Angle Neutron Scattering (SANS), Rubinson, K. A.; Buhlmann, P.; Allison, T. C, Phys. Chem. Chem. Phys. 2016, 18, 9470-9475. full text
New Perspectives on Silver Nanowire Formation from Dynamic Silver Ion Concentration Monitoring and Nitric Oxide Production in the Polyol Process, Whitecomb, D. R.; Clapp, A. R.; Buhlmann, P.; Blinn, J. C.; Zhang, J., Cryst. Growth Des. 2016, 16, 1861-1868. full text
Ionic Liquids as Electrolytes for Electrochemical Double-Layer Capacitors: Structures that Optimize Specific Energy, Mousavi, M. P. S.; Wilson, B. E.; Kashefolgheta, S.; Anderson, E. L.; He, S.; Buhlmann, P.; Stein, A., ACS Appl. Mater. Interfaces 2016, 8, 3396-3406. full text
A Disposable Planar Paper-Based Potentiometric Ion-Sensing Platform, Hu, J.; Stein, A.; Buhlmann, P., Angew. Chem., Int. Ed. 2016, 55, 7544-7547. full text (Highlighted in C&E News)
Donnan Failure of Ion-Selective Electrodes with Hydrophilic High-Capacity Ion-Exchanger Membranes, Ogawara, S.; Carey III, J. L.; Zou, X. U.; Buhlmann, P., ACS Sensors, 2016, 1, 95-101. full text
Rational Design of All-Solid-State Ion-Selective Electrodes and Reference Electrodes, Hu, J.; Stein, A.; Buhlmann, P., TrAC, Trends Anal. Chem. 2016, 76, 102-114. (Tutorial review on solid-state potentiometric sensors) full text
Electrochemical Impedance Spectroscopy of Ion-Selective Membranes: Artifacts in Two-, Three-, and Four-Electrode Measurements, Anderson, E. L.; Buhlmann, P., Anal. Chem. 2016, 88, 9738–9745. full text
Ion Aggregation and N+-C-H NR3 Hydrogen Bonding in a Fluorous Phase, Anderson, E. L.; Gingery, N. M.; Boswell, P. G.; Chen, X. V.; Rabai, J., Buhlmann, P., J. Phys. Chem. B 2016, 120, 11239–11246. full text
Publications 2015
Potentiometric In Situ Monitoring of Anions in the Synthesis of Copper and Silver Nanoparticles Using the Polyol Process, Carey III, J. L.; Whitcomb, D. R.; Chen, S.; Penn, L.R.; Buhlmann, P., ACS Nano 2015, 9, 12104-12114. full text
Electrochemical Stability of Quaternary Ammonium Cations: An Experimental and Computational Study, Mousavi, M. P. S.; Kashefolgheta, S.; Stein, A.; Bühlmann, P., J. Electrochem. Soc. 2015, 163, H74-H80. full text
Unbiased Quantification of the Electrochemical Stability Limits of Electrolytes and Ionic Liquids, Mousavi, M. P. S.; Dittmer, A. J.; Wilson, B. E.; Stein, A.; Bühlmann, P., J. Electrochem. Soc. 2015, 162, A2250-A2258. full text
Dynamic Silver Speciation as Studied with Fluorous-Phase Ion-Selective Electrodes: Effect of Natural Organic Matter on the Toxicity and Speciation of Silver, Mousavi, M. P. S.; Gunsolus, I. L.; Pérez de Jesús, C. E.; Lancaster, M.; Hussein, H.; Haynes, C. L.; Buhlmann, P., Sci. Total Environ. 2015, 537, 453-461. full text
All-Solid-State Reference Electrodes Based on Colloid-Imprinted Mesoporous Carbon and Their Application in Disposable Paper-based Potentiometric Sensing Devices, Hu, J.; Ho, K. T.; Zou, X. U.; Smyrl, W. H.; Stein, A.; Bühlmann, P. Anal. Chem., 2015, 87, 2981–2987. full text
Ion-Selective Electrodes and Reference Electrodes with a Solid Contact Having Mesoporous Carbon, Hu, J.; Stein, A.; Buhlmann, P. U.S. Patent Application: 14/716,564. Filed on May 2015
Ionic Liquid Reference Electrodes With a Well-Controlled Co(II)/Co(III) Redox Buffer as Solid Contact, Zou, X. U.; Chen, L. D.; Lai, C.-Z.; Bühlmann, P., Electroanalysis 2015, 27, 602–608. full text
In Situ Atomic Resolution Studies of the Electrode/Solution Interface By Electrochemical Scanning Tunneling Microscopy, Thorgaard, S. N.; Buhlmann, P., In Nanoelectrochemistry, Mirkin, M. V.; Amemiya, S., Eds.; CRC Press, London, 2015, pp 695–748. full text
Electrochemical Reduction of 2,4-Dinitrotoluene in Aprotic and pH-Buffered Media, Olson, E. J.; Isley, W. C., III; Brennan, J. E.; Cramer, C. J.; Bühlmann, P. J. Phys. Chem. C 2015, 119, 13088–13097. full text
Effects of Humic and Fulvic Acids on Silver Nanoparticle Stability, Dissolution, and Toxicity, Gunsolus, I. L.; Mousavi, M. P. S.; Buhlmann, P., Haynes, C. L. Environ. Sci. Technol. 2015, 49, 8078–8086. full text
Hierarchically Porous Polymer Monoliths by Combining Controlled Macro- and Microphase Separation, Saba, S. A.; Mousavi, M. P. S.; Bühlmann, P.; Hillmyer, M. A., J. Am. Chem. Soc. 2015, 137, 8896–8899. full text
Publication 2014
Calibration-Free Ionophore-Based Ion-Selective Electrodes With a Co(II)/Co(III) Redox Couple-Based Solid Contact, Zou, X. U.; Zhen, X. V.; Cheong, J. H.; Bühlmann, P. Anal. Chem., 2014, 86, 8687–8692.
Paper-Based Potentiometric Ion Sensing, Lan, W.; Zou, X. U.; Hamedi, M. M.; Hu, J.; Parolo, C.; Maxwell, E. J.; Bühlmann, P.; Whitesides, G. M. Anal. Chem. 2014, 86, 9548–9553.
Ion-Selective Electrodes with Colloid-Imprinted Mesoporous Carbon as Solid Contact, Hu, J.; Zou, X. U.; Stein, A.; Bühlmann, P., Anal. Chem. 2014, 86, 7111–7118.
Paper-Based Reference Electrode and Potentiometric Ion Sensing, Wan, W.; Maxwell, E.; Parolo, C.; Bwambok, D.; Thuo, M.; Subramaniam, A.; Whitesides, G.; Zou, X.; Hu, J.; Buhlmann, P. WO1 patent application 0042697.00391, April 2014
Publications 2013
Three Dimensionally Ordered Mesoporous (3DOm) Carbon Materialas Electrodes for Electrical Double-Layer Capacitors with Ionic Liquid Electrolytes, Anh Vu, Xiaoyue Li, John Phillips, Aijie Han, William H. Smyrl, Philippe Bühlmann, Andreas Stein Chem. Mater., Accepted, September 2013.
Reference Electrodes with Salt Bridges Contained in Nanoporous Glass: An Underappreciated Source of Error, Maral P.S. Mousavi and Philippe Bühlmann, Anal. Chem. 2013, 85 (19), pp 8895–8901
Solid Contact Ion-Selective Electrodes With a Well- Controlled Co(II)/Co(III) Redox Buffer Layer;Xu U. Zou , Jia H. Cheong , Brandon James Taitt , and Philippe Bühlmann, Anal. Chem., 2013, 85 (19), pp 9350–9355.
Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Level Detection and In-Situ Monitoring of Adsorption onto Sand; Chen, L. D.§ ; Lai, C.-Z.§ ; Granda, L. P. ; Fierke, M. ; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P., Anal. Chem,.2013, 85 (15), pp 7471–7477.(§These authors contributed equally to this work)
Characterization of Silver Ion Dissolution from Silver Nanoparticles using Fluorous-phase Ion-selective Electrodes and Assessment of Resultant Toxicity to Shewanella oneidensis: Melisa A. Maurer-Jones, Maral P. S. Mousavi, Li D Chen, Philippe Buhlmann, Christy Haynes, Chem. Sci., 2013, 4, 2564-2572
Current Pulse Based Reference Electrodes Without Liquid Junctions; Zou, Xu; Buhlmann, Philippe, Anal. Chem., 2013, 85 (8), pp 3817–3821
Lifting of the (√3 x 22) Surface Reconstruction of Au(111) in Halide Solutions as a Sensitive Probe to Monitor Adsorption of Cyclodextrin and Its Complexes; Thorgaard, S. N.; Bühlmann, P., Journal of Electroanalytical Chemistry, 2013, 693, pp1-8
Quenching Performance of Surfactant-containing and Surfactant-free Fluorophore-doped Mesoporous Silica Films for Nitroaromatic Compound Detection, Anh Vu, John Phillips, Philippe Bühlmann, and Andreas Stein, Chemistry of Materials, 2013, 25 (5) pp 711-722.
Unbiased Assessment of Electrochemical Windows: Minimizing Mass Transfer Effects on the Evaluation of Anodic and Cathodic Limits, Olson E. J. Bühlmann, P., Journal of the Electrochemical Society, 2013, 160 (2) ppA320-A323.
Publications 2012
A Highly Selective Cyanide-Selective Electrode Based on Zn(II) Tetraphenylporphyrin as Ionophore, Chen, L. D.;Zou, Xu U ;Bühlmann, P., Anal. Chem., 2012, 84 (21), pp 9192–9198
Receptor-Based Detection of 2,4-Dinitrotoluene using Modified Three-Dimensionally Ordered Macroporous Carbon Electrodes, Fierke, M.; Olson, E. J., Bühlmann, P.; Stein, A., ACS Appl. Mater. Interfaces, 2012, 4 (9), pp 4731–4739
Advantages and Limitations of Reference Electrodes with an Ionic Liquid Junction and Three-Dimensionally Ordered Macroporous Carbon as Solid Contact, Zhang, Tiantian; Lai, Chun-Ze; Fierke, Melissa; Stein, Andreas; Buhlmann, Philippe, Anal. Chem., 2012, 84 (18), pp 7771–7778
Ion-Selective Electrodes With Ionophore-Doped Sensing Membranes. In Supramolecular Chemistry: From Molecules to Nanomaterials; Steed, A. W., Ed, Gale P. A., Ed; John Wiley & Sons, Ltd: New York, 2012; Vol. 5, p 2539.(www.wileyonlinelibrary.com/ref/smc)
Self-assembled monolayers formed by 5,10,15,20-tetra(4-pyridyl)porphyrin and cobalt 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine on iodine-passivated Au(1 1 1) as observed using electrochemical scanning tunneling microscopy and cyclic voltammetry, Thorgaard, S. N.; Bühlmann, P., Journal of Electroanalytical Chemistry, 664, 2012, 94–99.
Ion-Selective Electrodes with Unusual Response Functions: Simultaneous Formation of Ionophore-Primary Ion Complexes with Different Stoichiometries, Miyake, M; Chen, L. D.; Pozzi, G; Bühlmann, P,Anal. Chem., 2012, 84 (2), pp 1104–1111
Publications 2011
Potentiometric Sensors Based on Fluorous Membranes Doped with Highly Selective Ionophores for Carbonate, Chen, L. D.; Mandal, De; Pozzi, G; Gladysz, J.; Bühlmann, P, J. Am. Chem. Soc., 2011, 133 (51), pp 20869–20877
Getting More Out of a Job’s Plot: Determination of Reactant:Product Stoichiometry in Cases of Displacement Reactions and n:n Complex Formation, Olson, E.; Bühlmann, P. J. Org. Chem., 2011, 76 (20), 8406–8412.
Interaction of a Weakly Acidic Dinitroaromatic with Alkylamines: Avoiding the Meisenheimer Trap, Olson, E.; Xiong, T.; Cramer, C.J.; Bühlmann, P. JACS, 2011, 133 (32), 12858-12865.
Voltage-induced chemical contrast in scanning tunneling microscopy using tips chemically modified with hydrogen bond donors, Gingery, D.; Bühlmann, P., Surf. Sci.2011, 605, 1099–1102.
Publications 2010
Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes, Lai, C.-Z.; Fierke, M. A.; Corrêa da Costa, R.; Gladysz, J. A.; Stein, A.; Bühlmann, P., Anal. Chem. 2010, 82, 7634–7640.
Redox Pontial and C-H Bond Cleaving Properties of a Nonheme Fe IV=O Complex in Aqueous Solution, Wang , D.; Zhang, M.; Bühlmann, P.; Que, L., Jr., J. Am. Chem. Soc.2010, 132, 7638–7644.
Chemical Stability and Application of a Fluorophilic Tetraalkylphosphonium Salt in Fluorous Membrane Anion-Selective Electrodes, Chen, L. D.; Mandal, D.; Gladysz, J. A.; Bühlmann, P., New J. Chem. 2010, 34, 1867–1874.
Minimizing Solvent Waste in the Undergraduate Analytical Lab: A Microcell for Cyclic Voltammetry , Olson, E. J., Bühlmann, P. J. Chem. Ed., 2010, 87, 1260–1261
Bromine-Passivated Au(111) as a Platform for the Formation of Organic Self-Assembled Monolayers Under Electrochemical Conditions, Thorgaard, S. N.; Bühlmann, P., Langmuir 2010, 26, 7133–7137.
Electrochemistry with Media of Exceptionally Low Polarity: Voltammetry in a Fluorous Solvent, Olson, E. J.; Boswell, P. G.; Givot, B. L.; Yao, L.; B ü hlmann, P., J. Electroanal. Chem. 2010 , 639, 154–160.
Effects of Architecture and Surface Chemistry of Three-Dimensionally Ordered Macroporous Carbon Solid Contacts on Performance of Ion-Selective Electrodes, Fierke, M. A.; Lai, C.-Z., Bühlmann, P., Stein, A., Anal. Chem. 2010 , 82, 680–688. Abstract
Cation-Coordinating Properties of Perfluoro-15-Crown-5, Lai, C.-Z.; Reardon, M. E.; Boswell, P. G.; Buhlmann, P., J. Fluor. Chem.2010, 131, 42–46.
Publications 2009
Fluorous Polymeric Membranes for Ionophore-Based Ion-Selective Potentiometry, Lai, C.-Z.; Koseoglu, S. S.; Lugert, E. C.; Boswell, P. G.; Rábai, J.; Lodge, T. P.; Bühlmann, P., J. Am. Chem. Soc. 2009, 131, 1598–1606.
Subnanomolar Detection Limit Application of Ion-Selective Electrodes with Three-Dimensionally Ordered Macroporous (3DOM) Carbon Solid Contacts, Lai, C.-Z.; Joyer, M. M.; Fierke, M. A.; Petkovich, N. D.; Stein, A.; Buhlmann, P., J. Solid State Electrochem 2009, 13, 123–128.
Structure Determination of Organic Compounds–Tables of Spectral Data, Pretsch, E.; Bühlmann, P.; Badertscher, M., 4 th, revised and enlarged edition, Springer Verlag: Berlin, Heidelberg, New York, 2009.
{German translation published 2010.}
Publications 2008
Formation of gold nanoparticles on multiwalled carbon nanotubes by thermal evaporation, Gingery, D.; Bühlmann, P., Carbon2008, 46, 1966–1972.
Preparation of a Highly Fluorophilic Phosphonium Salt and its Use in a Fluorous Anion-Exchanger Membrane with High Selectivity for Perfluorinated Acids, Boswell, P. G.; Anfang, A. C.; Bühlmann, P., J. Fluor. Chem.2008, 129, 961–967.
Assessment of Density Functionals, Semiempirical Methods, and SCC-DFTB for Protonated Creatinine Geometries, Settergren, N. M., Bühlmann, P.; Amin, E. A., J. Mol. Struct. Theochem., 2008, 861, 68–73.
Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity, Boswell, P. G.; Szíjjártó, C.; Jurisch, M.; Gladysz, J.; R á bai, J.; B ü hlmann, P., Anal. Chem. 2008, 80, 2084-2090 .
Effect of Spacer Geometry on Oxoanion Binding by Bis- and Tetrakis-Thiourea Hosts, Leung, A. N.; Degenhardt, D. A.; Bühlmann, P. Tetrahedron 2008, 64, 2530–2536.
Plasticization of Amorphous Perfluoropolymers, Lugert, E. C.; Lodge, T. P., Bühlmann, P., J. Polym. Sci. B.: Polym. Phys. 2008, 46, 516–525.
Response Mechanism of Ion-Selective Electrodes Based on a Guanidine Ionophore: An Apparently “Two-Thirds Nernstian” Response Slope, Koseoglu, S. S.; Lai, C.-Z.; Ferguson, C.; Bühlmann, P.. Electroanalysis, 2008, 20, 331–339.